A short and simple explanation

A potentiostat is an electronic device that measures and controls the potential (or voltage) difference between two electrodes.

portable potentiostats from PalmSens

Potentiostat

A potentiostat is an electronic device that measures and controls the potential (or voltage) difference between two electrodes.

The measuring electrodes can be very small like micro-electrodes in a conductive solution, but also a coated metal coupon in an acidic environment. A three-electrode setup is also possible.

A potentiostat can be used in the fields of electrochemistry and biochemistry, but also sensor development and battery research.

Video

What is a potentiostat, why use it and how to connect?

In this video we’ll be talking about what a potentiostat, galvanostat and a frequency analyzer are, why you would use them, and how to connect the electrodes.

You can see examples of classic and screen-printed electrodes and four different types of electrochemical techniques.

See all video's on potentiostats
Why use it?

Advantage of a potentiostat

The word potentiostat comes from potential. In electronics and electrochemistry a potential is stored energy or the “potential to do work”.

Applying a potential with a potentiostat, for instance a PalmSens4, to a conducting surface in a conducting solution can induce a particular electrode current which is measured by the potentiostat while keeping the applied potential constant.

The advantage of a potentiostat is that it has complete control over the applied potential, unlike a normal power source.

potentiostat
A tiny potentiostat that can be connected to your mobile phone for measurements outside the lab.
Application areas

What is a potentiostat used for?

A potentiostat is used mainly in electrochemistry. For example, electrochemical researchers want to show how much lead or other heavy metals are present in drinking water (Figure 1), how much iron there is in blood or investigate how rainwater affects the surface of a certain metal (e.g. resulting in corrosion).

Figure 1 | Heavy metal detection

 

Explained

How does a potentiostat work?

A potentiostat applies potential to a certain surface, an electrode. The amount of electrons on the surface is thereby reduced or increased. This causes the liquid to be triggered to deliver or consume electrodes to compensate for this.

The exchange of electrons per time, the electrode’s current, can be measured by the potentiostat. This is usually done in a three-electrode setup (Figure 2).

Scheme of a 3-electrode setup for a potentiostat

Figure 2 | Scheme of a 3-electrode setup for a potentiostat

An electrode made to deliver current of a certain substance is present is called a sensor. This sensor has a certain sensitivity to the substance that you want to measure.

For this reason, there are many different sensors that react in different ways to certain chemical substances.

Sometimes a sensor can be used multiple times, but often they are disposable, so for a one-time use, and the sensor is permanently changed by the reactions happening at the electrodes.

In addition to potentiostats, PalmSens sells sensors of all shapes and sizes for all kinds of measurements.

Sensors
Types

Different types

There are several types of potentiostats used by electrochemical researchers.

  • Most researchers in a university or laboratory use a potentiostat to detect all sorts of possible substances in fluid (for example, the PalmSens4)
  • But there are also potentiostats that are only used to detect one particular substance. For this purpose PalmSens makes potentiostat modules, so-called OEM potentiostats.
  • PalmSens also provides tailored potentiostats for specific applications like the EmStat Go.
different types of potentiostats
Figure 3 | Different types of potentiostats
Download Potentiostat Overview
potentiostat software

Potentiostat software

Without associated software, there is little to do with your portable potentiostat. PalmSens portable potentiostats are sold including intuitive software, which makes it easy to get started and it can be installed on multiple computers and laptops.

PalmSens also provides an app for Android devices, you can download this free of charge in the Google Play Store.

You can also use all of the currently available spreadsheet software that is useful for creating charts using the Export Data functionality in PSTrace.

About software
Costs

Potentiostat prices

Portable potentiostats usually come at a certain price. However, PalmSens managed to develop a series of portable potentiostats that are highly affordable, definitely with all the given specifications.

E-mail us for a quotation or call us to discuss the possibilities for your research with us.

Request a quotation
Techniques

Potentiostat techniques

Overview of electrochemical techniques that can be performed using a potentiostat.

Voltammetric techniques

Pulsed techniques

Galvanostatic techniques

Amperometric techniques

Potentiostatic/Galvanostatic Impedance spectroscopy (EIS/GEIS)

Other techniques

Linear Sweep Voltammetry (LSV)

Differential Pulse Voltammetry (DPV)

Linear Sweep Potentiometry (LSP)

Chronoamperometry (CA)

Potential scan or current scan

Mixed Mode (MM)

Cyclic Voltammetry (CV)

Square Wave Voltammetry (SWV)

Chronopotentiometry (CP)

Zero Resistance Amperometry (ZRA)

Fixed potential or fixed current

 

Fast Cyclic Voltammetry (FCV)

Normal Pulse Voltammetry (NPV)

MultiStep Potentiometry (MP)

Chronocoulometry (CC)

Time scan

 

AC Voltammetry (ACV)

 

Open Circuit Potentiometry (OCP)

MultiStep Amperometry (MA)

   
   

Stripping Chronopotentiometry (SCP or PSA)

Fast Amperometry (FAM)

   
     

Pulsed Amperometric Detection (PAD)

   
     

Multiple-Pulse Amperometric Detection (MPAD)

   

 

Definition

Definition of a potentiostat

Potentiostat
An electronic device that measures and controls the potential (or voltage) difference between two electrodes is called a potentiostat. The advantage of a potentiostat is that it has complete control over the applied potential, unlike other power sources, while measuring the response current.

Frequently Asked Questions

What is a potentiostat?

The word potentiostat comes from potential. In electronics and electrochemistry a potential is stored energy or the “potential to do work”.

Applying a potential with a potentiostat, for instance a PalmSens4, to a conducting surface in a conducting solution can induce a particular electrode current which is measured by the potentiostat while keeping the applied potential constant.

The advantage of a potentiostat is that it has complete control over the applied potential, unlike a normal power source.

Which potentiostat do I need?

An electrochemist typically spends many months together with a potentiostat to get research done. The potentiostat’s performance should not limit the results and the software should be user friendly and easy to use. Here are six factors to consider before buying a potentiostat. Read more

What is a potentiostat used for?

A potentiostat is used mainly in electrochemistry. For example, electrochemical researchers want to show how much lead or other heavy metals are present in drinking water, how much iron there is in blood or investigate how rainwater affects the surface of a certain metal (e.g. resulting in corrosion). Read more…

How does a potentiostat work?

A potentiostat applies potential to a certain surface, an electrode. The amount of electrons on the surface is thereby reduced or increased. This causes the liquid to be triggered to deliver or consume electrodes to compensate for this. The exchange of electrons per time, the electrode’s current, can be measured by the potentiostat. This is usually done in a three-electrode setup (Figure 2).

An electrode made to deliver current of a certain substance is present is called a sensor. This sensor has a certain sensitivity to the substance that you want to measure. For this reason, there are many different sensors that react in different ways to certain chemical substances.

Sometimes a sensor can be used multiple times, but often they are disposable, so for a one-time use, and the sensor is permanently changed by the reactions happening at the electrodes.

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