Electrochemistry explained

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Polarization Curves: setup, recording, processing and features

In this extensive section Polarization Curves are discussed. How to setup your equipment, the choice of parameters as well as the data processing is discussed. This will enable you to record a polarization curve and extract the corrosion rate from it by using PSTrace 5. Furthermore, the polarization curves and Evan’s diagrams for passivation films (thick and thin) are discussed. This section closes with a brief description of crevice and pitting corrosion.

Capacitive Current

If the potential of the electrode is changed, for example during a potential step, the amount of charge the capacitor stores changes, and a current will flow that has no chemical but only a physical meaning. This is the current that charges or discharges the capacitor also known as capacitive charging current or short capacitive current.