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Troubleshooting on potentiostat experiments

Here are some general comments on trouble shooting that are valid for any experiment. We made this list to enable even not very experienced users to find the sources of trouble as soon as possible to keep the frustration level for you and coworkers as low as possible.

History of the potentiostat

Knowing the history of a device is helpful to understand certain terminologies or identify obsolete parts of a device that are still used because this is how it was always done.

Polarization Curves: setup, recording, processing and features

In this extensive section Polarization Curves are discussed. How to setup your equipment, the choice of parameters as well as the data processing is discussed. This will enable you to record a polarization curve and extract the corrosion rate from it by using PSTrace 5. Furthermore, the polarization curves and Evan’s diagrams for passivation films (thick and thin) are discussed. This section closes with a brief description of crevice and pitting corrosion.

Capacitive Current

If the potential of the electrode is changed, for example during a potential step, the amount of charge the capacitor stores changes, and a current will flow that has no chemical but only a physical meaning. This is the current that charges or discharges the capacitor also known as capacitive charging current or short capacitive current.

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